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Common irritants that are important causes of occupational dermatitis (tailored from <>6, 66, 188]) Water and its components (Salts and oxides of calcium, magnesium, and iron) Skin cleansers Soaps, detergents, “waterless cleansers, ”and components (sand, silica) Industrial cleansing Detergents, surface-lively agents, brokers sulfonated oils, wetting brokers, emulsifiers, enzymes Alkalis Soap, soda, ammonia, potassium and sodium hydroxides, cement, lime, sodium silicate, trisodium phosphate, and various amines Acids Severe irritancy (caustic): sulfuric, hydrochloric, nitric, chromic, and hydrofluoric acids Moderate irritancy: acetic, oxalic, and salicylic acids Oils Cutting oils with numerous components (water, emulsifiers, antioxidants, anticorrosive brokers, preserva- tives, dyes and perfumes) Lubricating and spindle oils Organic solvents White spirit, benzene, toluene, trichloroethylene, perchloroethylene, methylene chloride, chloro- benzene Methanol, ethanol, isopropanol, propylene glycol Ethyl acetate, acetone, methyl ethyl ketone, ethylene glycol monomethyl ether, nitroethane, turpen- tine, carbon disulfide Thinners (mixtures of alcohols, ketones, and toluene) Oxidizing brokers Hydrogen peroxide, benzoyl peroxide, cyclohexanone peroxide, sodium hypochlorite Reducing brokers Phenols, hydrazines, aldehydes, thioglycolates Plants Citrus peel and juice, flower bulbs, garlic, onion, pineapple, pelargonium, iris, cucumbers, butter- cups, asparagus, mustard, barley, chicory, corn Various crops of the spurge household (Euphorbiaceae), Brassicaceae household (Cruciferae) and Ranun- culaceae family (for further particulars see <sixty>one]) Animal products Pancreatic enzymes, bodily secretions Miscellaneous irritants Alkyl tin compounds and penta-, tetra-, and trichlorophenols (wooden preservatives) Bromine (in gasoline, agricultural chemical substances, paper trade, flame retardant) Methylchloroisothiazolinone and methylisothiazolinone (irritant at high concentrations during manufacturing or misuse) Components of plastic processing (formaldehyde, phenol, cresol, styrene, di-isocyanates, acrylic monomers, diallyl phthalate, aliphatic and aromatic amines, epichlorohydrin) Metal polishes Fertilizers Propionic acid (preservative in animal feed) Rust-preventive products Paint removers (alkyl bromide) Acrolein, crotonaldehyde, ethylene oxide, mercuric salts, zinc chloride, chlorine 262 Peter J. 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